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In accordance to our calculations, the lowest energy triplet spin-state isomer of the anionic boron pentamer cluster has C2 symmetry, and consequently, it should show optical activity. Finally, we have studied the change of the geometrical structure of the boron pentamer clusters from planar to compact three-dimensional structures caused by the bonding of ligands to the boron atoms. Our explicit all-electron calculations have been rationalized in terms of the shell-closure of the delocalized valence orbitals of the clusters as predicted