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Intermediate-level radioactive waste (ILW) includes cellulosic materials, which under the hyperalkaline conditions expected in a cementitious geological disposal facility (GDF), will undergo abiotic hydrolysis forming a variety of soluble organic species. Isosaccharinic acid (ISA) is a notable hydrolysis product, being a strong metal complexant that may enhance the transport of radionuclides to the biosphere. This study shows that irradiation with 1 MGy of γ-radiation under hyperalkaline conditions enhances the rate of ISA production f
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