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The decomposition products of HIPS were hydrocarbons, carbon dioxide and water. Meanwhile, brominated flame retardants and antimony trioxide added to the HIPS were also debrominated and recovered. Without secondary pollution, the SCWO process developed in this study could effectively achieve decomposition of HIPS resins, debromination of brominated flame retardants and recovery of antimony trioxide in one procedure.Picloram (PCR), a vastly utilized chlorinated herbicide, is very stable in water and soil with severe ecological and health