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85Se, Gr, and Co0.85Se/Gr were obtained for rear-side illumination and additionally for front- and rear-side illuminations (AM 1.5, 100 mW/cm2) using different electrolytes. As the cobalt-based electrolyte of [Cbpy)3]2+/3+ exhibited a low light absorption and low overpotential for dye regeneration, a rear-side illuminated DSSC with a cobalt-based electrolyte showed the highest efficiency of 9.43 ± 0.02%, which is greater than that of the DSSC with an I-/I3--based electrolyte (η = 7.63 ± 0.04%).The current work showcases general princip