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By using this method, we provide an efficient way to a wide variety of substituted thiolic compounds. Moreover, the catalyst is easily recovered using simple filtration and reused for 5 consecutive runs. CONCLUSION In this effort we developed a new Pd catalyst bonded on the surface of zeolite as substrate to prepare heterogeneous catalyst. We demonstrate that this novel catalyst offers reliable and convincing data that may offer valuable application in further developing the science and technology of Ullmann reaction protocols and allie