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Herein, we review the latest developments that have been made in self-healing materials and puts advancing insights into the fabrication of SH-PNCs in which the combination of covalent bonds and non-covalent interactions provides an optimal balance between their mechanical performance and self-healing capability. We highlight the importance of specific entropic, enthalpic changes, polymer chain conformations and flexibility that enable the reconstruction of damaged surface and physical reshuffling of dynamic bonds at the interface of cut