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This mechanically induced structural transformation coincided with the dissociative surface reaction between hydrogen (oxygen) gas molecules and sp2 carbon-carbon bonds that are highly strained, which results in the formation of carbon-hydrogen groups (carbonyl or ether groups together with silicon atoms having higher oxidation states). On the basis of variations of the fraction of these surface functional groups with gas pressure, a phenomenological model is proposed for the gas pressure dependence of friction for steel when sliding on