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A tandem catalytic process for 1,3- and 1,4-bisarylation of donor-acceptor (D-A) cyclopropanes and cyclobutanes is disclosed. This strategy capitalizes on the use of two distinct sources of nucleophilic and electrophilic arylating agents, affording the formation of two new C-C bonds in an orchestrated multicomponent fashion with the aid of a catalytic Lewis acid. Mechanistic investigations have revealed it to be a stereoselective process, and products could be easily elaborated into other useful compounds.ConspectusThe catalytic asymme