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Hydrates have high-potential as stage change materials (PCMs) for the use as a thermal power storage space medium. To produce thermal power storage space technology making use of a hydrate-based material, further investigation of thermophysical properties and the collection of a suitable hydrate are expected. Tetrabutylphosphonium oxalate (TBPOx) ionic semiclathrate hydrate contains oxalic acid in sodium kind, as a guest chemical, which will be classified as carboxylic acid