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The results provide evidence that Leucaena exhibited greater sensitivity to O3 during initial exposure (up to 12 months) but showed moderate tolerance by the end of the 2nd year.The combined use of capping (lanthanum modified bentonite; LM and oxidizing (calcium nitrate; CN) agents was investigated to immobilize arsenic (As) in sediments. The vertical changes in labile As and dissolved As were measured using diffusive gradients in thin films (DGT) and Rhizon devices. The results showed that the combined application of LMB and CN had t