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It can be concluded that due attention should be paid to the efficient removal technology and mechanism for polymer-Cr complexes, as well as the oxidation intermediates in the role of conversion and removal of Cr species. The pipe deposits from water distribution network are iron-wastes, which could be used as a catalyst of advanced oxidation processes (AOPs). This paper prepared one main composition (α-FeOOH) of pipe deposits and compared the difference of chloramphenicol (CAP) degradation by α-FeOOH-activated hydrogen peroxide/persulfa