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Confocal imaging with fluorescent-labeled polymer solutions was used to explore the underlying migration behavior. A surprising outcome of our results is the formation of cross-sectionally nonuniform viscoelasticity that may have unique applications in microfluidic particle focusing.The gas-phase reaction of N2O5 with NH3 under tropospheric conditions has been carried out employing quantum chemical calculations at the CCSD(T)/CBS//MP2/aug-cc-pVTZ level of theory. The activation barrier of the reaction was found to be 13.5 kcal mol-1 wi