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This study can provide a good feasibility for large-scale applications of UF-based or PBS-based composites and nano-composites used as slow-release fertilizers or other products in agriculture or horticulture.Hydrogen-bonded organic frameworks (HOFs) show great potential in many applications, but few structure-property correlations have been explored in this field. In this work, we report that self-assembly of a rigid and planar ligand gives rise to flat hexagonal honeycomb motifs which are extended into undulated two-dimensional (2D) la