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The kinetics of the photolysis reaction follows first-order kinetics (k = 0.1/h). After thiolphenol (C6H5SH) ligand functionalization of the generated silver clusters in aqueous solution, the low or high resolution mass spectra showed the constant species composites with a molecular formula AgnLn-1 (n = 2-9 and L = C6H5S). More evidence indicated the formation of polymer-wrapped silver clusters. Their antibio property was explored, and we confirmed that they indeed show efficient activity.Excitons play major roles in optical processes in modern semiconducto