https://www.selleckchem.com/pr....oducts/sar439859.htm
OCS binding to and reactivity with isolated gold cluster cations, Aun+ (n = 1-1, has been studied by infrared multiple photon dissociation (IR-MPD) spectroscopy in conjunction with quantum chemical calculations. The distribution of complexes AunSOCS)m+ formed reflects the relative reactivity of different cluster sizes with OCS, under the multiple collision conditions of our ablation source. The IR-MPD spectra of Aun(OCS)+ (n = 3-1 clusters are interpreted in terms of either μ1 or μ2 S binding motifs. Analysis of the fragmentatio
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