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This study highlights the potential of this methodology for the quantitative determination of photoinduced radical generation efficiency used in many fields of applications.The poor water resistance property of a commercial Mn4+-activated narrow-band red-emitting fluoride phosphor restricts its promising applications in high-performance white LEDs and wide-gamut displays. Herein, we develop a structural rigidity-enhancing strategy using a novel KHF2Mn4+ precursor as a Mn source to construct a proton-containing water-resistant phosphor