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Overall, our study reveals that with their dynamically stable 1T- and 1H-phases, single-layers of CaX2 crystals can be alternative ultra-thin insulators.A series of experiments demonstrates that strong light-matter coupling between vibrational excitations in isotropic solutions of molecules and resonant infrared optical microcavity modes leads to modified thermally activated kinetics. However, Galego et al. [Phys. Rev. X 9, 021057 (2019)] recently demonstrated that, within transition state theory, effects of strong light-matter couplin