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The unassisted water-splitting efficiency of 11.31%, measured without separating the evolved gases, is achieved using a device composed of three series-connected silicon solar cells and an NiFe-LDH/Cu/Ni-foam counter electrode in a highly alkaline electrolyte.As the earth's third most abundant element with various industrial applications, aluminum (Al) has received increasing concerns over its potential adverse health effects. Although Al exposure has been suggested to increase the risks of type 2 diabetes, little has been done to explo