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We expect that discussion of the thermochromic behavior will provide a new analysis perspective for the molecular design of o-carborane derivatives. The development of an interface to analyze liquid sample streams with direct analysis in real time mass spectrometry (DART-MS) is of great interest for coupling various analytical techniques, using non-volatile salts, with MS. Therefore, we devised an enclosed ionization interface and a sample introduction system for the versatile analysis of liquid samples with DART-MS. The sa