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In terms of typical gas products, benzene-alcohol enhanced the release of carbon dioxide, and hot water enhanced the water generation from dehydration reactions and slightly increased the production of carbon monoxide, while sodium hydroxide promoted the formation of methane at the early stage under 280 °C and later stage over 460 °C during the pyrolysis of eucalyptus wood. It is believed that the extraction pretreatment can not only obtain the bioactive extractive products but also benefit the pyrolysis process by lowering the energy b