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We used the cobalt-mediated radical copolymerization (CMRP) of ethylene and cyclic ketene acetals (CKAs) to efficiently incorporate ester groups into PE backbone as cleavable structures to create PE-based copolymer degradable under moderate conditions. The content of ethylene and ester units within the produced copolymer might be carefully regulated by CKA concentration or ethylene pressure. Also, the copolymerization of ethylene and CKA with other useful plastic monomers can produce functional and degradable PE-based copolymer. M
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