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The analysis of the enthalpy changes for vaporization (ΔHvap) of Al-based metallic glass (MG) can provide insight into the origin of the MG's glass forming ability (GFA). The ΔHvap of three Al-based MGs, Al84.5 ± Y10Ni5.5)15.5 ± x, Al85 ± Y8Ni5Co2)15 ± x, and Al86 ± Y4.5Ni6Co2La1.5)14 ± x, (hereafter referred to as AYNx, AYNCx, and AYNCLx, respectively), is analyzed by measuring their weight losses below their glass transition temperatures. The relationship between ΔHvap and aluminum concentration exhibit minimum values in the rang