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Therefore, the excellent capacitive behaviors render the B, N-DHCM promising electrode materials for application in supercapacitors and other energy storage systems. Structure control is widely admitted as a feasible strategy to restrain volume change and enhance electrical conductivity for chalcogenide anode materials. Herein, three-dimensionally hierarchical structure Co0.85Se@N-doped graphene hybrid is well-designed and synthesized by a facile hydrothermal strategy and post-calcination. It is noted that, owing to the nanoscale Kirken