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Finally, a weak hysteresis loop is clearly observed at 2.0 K. This dilute magnetic selenide displays a direct bandgap at ∼1.54 eV, analyzed by the Tauc equation. Interestingly, the use of second-harmonic-generation temperature dependence shows a turning point at ∼20 ± 1 K, which precisely corresponds to the magnetic ordering temperature within the error bar, thereby demonstrating the versatility of the technique for probing magnetic phase transition.The principal components of the 13C chemical shift tensors for the ten crystallographi