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As an important predictor of academic achievement and an effective indicator of learning quality, academic engagement has attracted the attention of researchers. The present study explores the relationship among adolescent self-esteem and academic engagement, the mediating effect of academic self-efficacy, and the moderating effect of perceived social support. Four-hundred and eighty adolescents (M age = 14.92) from the Hebei Province of China were recruited to complete anonymous questionnaires. The results show that self-esteem positiv