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We report a combined in-solution and on-surface synthesis of this hitherto biggest triangulene homologue, [7]triangulene (C78H24), consisting of twenty-eight benzenoid bands fused in a triangular manner. We use low-temperature scanning tunneling microscopy to verify the substance framework of individual particles adsorbed on a Cu(111) area. While basic [7]triangulene into the gasoline period is predicted to possess an open-shell septet ground state; our
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