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We report the growth of CuS/ZnS (CZS) nanoparticles (NPs) on the graphene sheet by a facile green synthesis process. The CuS/ZnS-graphene (CZSG) nanocomposites exhibit enhanced visible light photocatalytic activity towards organic dye (methylene blue) degradation than that of CZS nanoparticles. To find the reason for the enhanced photo-activity, we propose a new photocatalytic mechanism where graphene in the CZSG nanocomposites acts as a 'photosensitizer' for CZS nanoparticles. This distinctive photocatalytic mechanism is noticeably different from a