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This study suggests that such thresholds might not be relevant in practice, if parameter changes are not slow. Furthermore, we show that due to the chaotic dynamics of complex systems there is no well-defined critical rate of parameter change, which severely limits the predictability of the qualitative long-term behavior. The results show that the safe operating space of elements of the Earth system with respect to future emissions might be smaller than previously thought.Nonequilibrium processes during solidification can lead to kineti