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Quantification of the gas streams from chemical systems such as catalytic reactors are routinely performed by on-line gas chromatography. Gas chromatographs used for this purpose are typically provided with a combination of thermal conductivity (TCD) and flame ionization (FID) detectors to be able to detect and quantify both permanent gases; COx, N2, H2, etc., and hydrocarbons. However, the accuracy of the quantification is hindered by the intrinsic limitations of each type of detector. Namely, TCD has low sensitivity and FID does not de