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Visible light induced photocatalysis converted solar energy to chemical energy in the form of hydrogen. g-C3N4 modified by thermal oxidation etching, doped S, and nonprecious metal cocatalyst CoS2 (CoS2@SCN) were used for photocatalytic hydrogen production. And then the charge transfer behavior and mechanism of various alcohol sacrificial agents on hydrogen evolution was analyzed by optical characterization, impedance analysis, Mott-Schottky, and photocurrent tests. The relationship between the structure and catalytic performance was a