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We use 80-cycle pulses from an industrial-grade laser amplifier to simultaneously drive molecular positioning and supercontinuum generation in a gas-filled capillary, making more than two octaves of coherent bandwidth and attaining 45-fold compression to a duration of 1.6 cycles. Because the enhanced nonlinearity is linked to rotational movement, the dynamics could be exploited for long-wavelength regularity conversion and compressing picosecond lasers.High-refractive index nanostructured dielectrics