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Both factors are crucial for the consequent behavior of the YSR state.Solvothermal technology shows great promise in "green" materials synthesis, processing, and recycling. The outcome of a specific solvothermal reaction depends strongly on the solvent properties, and the versatility of solvothermal synthesis hinges on the very large changes in solvent properties as a function of temperature and pressure. Here, six simple 3d transition metal nitrate salts (Cu(ii), Ni(ii), Cii), Fe(iii), Mn(ii), Cr(iii)) were dissolved in five common so