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In this work, β-octa[(4-diethoxyphosphoryl)phenyl]porphyrin (2HOPPP) and its particular metal (Zn(II), Cd(II), Cu(II), and Ni(II)) buildings were ready in great yields. These very soluble chromophores were characterized in answer making use of spectroscopic (NMR, UV-vis, fluorescence), electrochemical, and spectroelectrochemical methods. Accessory associated with the electron-deficient residue (ArP(O)(OEt)2) towards the porphyrin macrocycle causes easier reductions and