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Due to photothermal conversion assistance, the hydrogen production rate of a-CNN nanosheets is promoted to 3.1 mmol g-1 h-1 compared to 0.71 mmol g-1 h-1 for a-CN, in which the NIR photothermal conversion is proven to contribute a 16% promotion to the hydrogen production. These findings suggest that creating an NIR photothermal conversion of photocatalysts by constructing "hot islands" can greatly promote photocatalytic hydrogen production.Spherical macromolecular assemblies, so-called latexes, consisting of polystyrene (PS) resemble a