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The MD results indicate that there surely is no obvious distinction between acoustic and optic vibrations when you look at the spectral range investigated in this work for the ionic fluids [N1114][NTf2] and [N1444][NTf2]. The analysis performed here agrees to some extent, but not entirely, with other propositions in the literary works, primarily from optical Kerr result (OKE) and FIR spectroscopies, concerning the intermolecular characteristics of ionic liquid