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The full total heat launch, complete smoke launch and complete carbon monoxide yield for TPU nanocomposite containing 4.0 wt% Ti3C2Tx-SCS nanohybrid were 58.0%, 58.4% and 75.8% lower than those of pristine TPU, respectively. Besides, the hierarchical TPU nanocomposite film containing 1.0 wt% Ti3C2Tx-SCS provided an averaged EMI shielding effectiveness of 21.3 dB in X band. This work provides a promising technique for fabricating fire safe and EMI sh