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These values are lower than PLQY and τ values for [Cu(POP)(6,6'-Me2bpy)][PF6] and [Cu(xantphos)(6,6'-Me2bpy)][PF6], and the investigation points to the 6,6'-dimethyl substitution pattern in the bpy ligand being critical for enhancement of the PLQY.Tumor tissue biopsy is often limited for non-small cell lung cancer (NSCLC) patients and alternative sources of tumoral information are desirable to determine molecular alterations such as anaplastic lymphoma kinase (ALK) rearrangements. Circulating tumor cells (CTCs) are an appealing component