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The Heisenberg trade coupling between a set of side extensions is determined because of the position associated with second naphtho group into the carbon anchor, therefore allowing ferromagnetic, antiferromagnetic, or nonmagnetic says. The periodic arrangement of edge extensions yields full spin-polarization at the band extrema, and the accompanying ferromagnetic floor state could be driven into nonmagnetic or antiferromagnetic phases through exterior stimuli. Overall, our work shows a precise tunability of the