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In order to study the role of Cu3P, electrochemical impedance spectroscopy (EIS) measurements were used to investigate the photogenerated charge properties of ZnS. The experiments of photocatalytic production of H2 confirm that the Cu3P co-catalysts effectively promote the separation of photogenerated charge carriers in ZnS, and consequently enhance the H2 evolution activity. The 3% Cu3P/ZnS sample delivers the highest catalyst activity and the consistent H2 evolution rate is14,937 µmol h-1 g-1cat, which is 10-fold boosted compared to th