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Sugarcane (Saccharum officinarum L.) cultivation leaves behind around 20 t ha-1 of biomass residue after harvest and processing. We investigated the potential for sequestering carbon (C) in soil with these residues by partially converting them into biochar (recalcitrant carbon-rich material). First, we modified the RothC model to allow changes in soil C arising from additions of sugarcane-derived biochar. Second, we evaluated the modified model against published field data, and found satisfactory agreement between observed and predicte