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he visible and NIR ranges have been determined. In the case of Sm-1, the values of QLnL in CH3OH and CD3OD solutions are exceptionally high, that is, 10.1(5) and 83(1) %. Values obtained for Yb-1, that is, 0.78(4) % in CH3OH and 8.4(1)% in CD3OD, are among the highest ones reported today for Yb3+ complexes formed with nondeuterated and nonhalogenated ligands.Using first-principles calculations, we investigate the electronic and topological properties of an antiferromagnetic (AFM) superatomic graphene lattice superimposed on a bipartite h