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In this work, we developed a novel strategy to couple chrysanthemum-like NiCo2S4in situ-grown MXene hybrids into a three-dimensional (3D) sandwich architecture hybrid as an electrode material for high-performance asymmetric supercapacitors and non-enzymatic H2O2 sensors. In the 3D sandwich architecture hybrid, the NiCo2S4 particles were encapsulated by MXene layers, which enhanced the interlayer space of MXene, significantly improving the electrochemical properties. In particular, the MXene/NiCo2S4 1 2 electrode achieved a specific capa