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The response of 5,10,15-tritolylcorrole with 3-dimethylaminoacrolein (3-DMA) and POCl3 gives a further example of the rebel reactivity with this contracted macrocycle. While no proof was gotten for the development for the expected β-acrolein corrole, the inner core substituted N21,N22-3-formylpropylcorrole and also the 10-acrolein isocorrole were the reaction services and products. By increasing the temperature or even the level of the Vilsmeier reagent, the 10-isocorrole became the unique effect item. The synt