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This spacer chain lengthening has a profound effect on the coordination of such ligand with Mn(II), further affecting the binding of oxdz. The inherent polarizable nature of the oxadiazole moiety and the presence of permanent pore of dimensions (19.122 × 19.253 Å2) in 1 have been exploited for the capture/removal of iodine not only from vapor and an organic solution but also from an aqueous media. It exhibits competent 100% reversible sorption of iodine with an uptake capacity of (1.1 ± 0.05) g/g of 1. The uptake value has been corrobor
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