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The nanoring structure of cycloparaphenylenes (CPPs) can be considered as the shortest fragment of a carbon nanotube. Herein, we successfully prepared a double-walled carbon nanoring of [6]CPP⊂[12]CPP, which can be regarded as the shortest double-walled carbon nanotube. [6]CPP⊂[12]CPP was constructed through the supramolecular assembly, and its crystallographic structure was unambiguously determined by single-crystal X-ray diffraction. The host-guest interaction and charge transfer in [6]CPP⊂[12]CPP were disclosed by UV-Vis absorption, fluorescence, and ele