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The reverse water gas shift reaction is a promising approach to solve the problem of excessive CO2 emission and energy shortage. However, insufficient charge separation efficiency of numerous semiconductor photocatalysts hamper their CO2 photoreduction performance. Defect engineering is considered as a desired method to tackle that shortcoming by the boosting the electron capture process. Herein, the sulfur vacancies-rich CdIn2S4 (VS-CdIn2S4) was synthesized by an efficient low-temperature plasma-enhanced technology. The outstanding VS-CdI