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The electrocatalytic activity regarding the multi-shelled CoxNi1-x oxide/phosphide is strongly dependent on the molar proportion of Co and Ni. In line with the connected benefits of complex structures and compositions, the multi-shelled Co0.5Ni0.5 oxide/phosphide displays outstanding electrocatalytic performance when it comes to large task and stable durability when it comes to OER, surpassing those of RuO2 and multi-shelled CoxNi1-x oxide/ph