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Idea involving biochemical methane prospective of downtown natural squander employing Fourier convert mid-infrared photoacoustic spectroscopy and multivariate examination. For circadian medicine to influence health, such as when to take a drug or undergo a procedure, a biomarker of molecular clock phase is required--one that is easily measured and generalizable across a broad population. It is not clear that any circadian biomarker yet satisfies these criteria. We analyzed 24-h m