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We review some of the past experimental work on these materials and illustrate new data using high resolution time of flight backscattering spectroscopy on organic-inorganic perovskites. We will show that the structural transitions in disordered lead based perovskites are driven by a broad frequency band of excitations. Creative Commons Attribution license.We predict a high thermoelectric efficiency of HfTe5, based on the first-principles calculations of the electronic structure and thermal conductivity, and the transport coefficients obt