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The presented workflow supports the characterization of different plant samples by automatic GIPC assignment, possibly ultimately causing the identification of the latest GIPCs. For the first time, computerized high-throughput profiling of those complex glycolipids is achievable by liquid chromatography-high-resolution tandem size spectrometry and subsequent automatic glycolipid annotation based on choice rules.The volatile amines trimethylamine (TMA) and dimethylamine (D